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Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals

《环境科学与工程前沿(英文)》 2022年 第16卷 第11期 doi: 10.1007/s11783-022-1581-0

摘要:

● The co-existing metals in WPCBs has positive catalytic influence in pyrolysis.

关键词: Waste printed circuit board     Catalyst     Pyrolysis     Kinetics    

Non-toxic, high selectivity process for the extraction of precious metals from waste printed circuit

《环境科学与工程前沿(英文)》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1723-z

摘要:

● Au, Ag and Pd were recovered from WPCBs with high efficiencies.

关键词: Thiosulfate     Printed circuit boards     Precious metals     Leaching     Hydrometallurgy    

Copper recovery from waste printed circuit boards concentrated metal scraps by electrolysis

Xiaonan Liu, Qiuxia Tan, Yungui Li, Zhonghui Xu, Mengjun Chen

《环境科学与工程前沿(英文)》 2017年 第11卷 第5期 doi: 10.1007/s11783-017-0997-4

摘要: Copper recovery is the core of waste printed circuit boards (WPCBs) treatment. In this study, we proposed a feasible and efficient way to recover copper from WPCBs concentrated metal scraps by direct electrolysis and factors that affect copper recovery rate and purity, mainly CuSO ·5H O concentration, NaCl concentration, H SO concentration and current density, were discussed in detail. The results indicated that copper recovery rate increased first with the increase of CuSO ·5H O NaCl, H SO and current density and then decreased with further increasing these conditions. NaCl, H SO and current density also showed a similar impact on copper purity, which also increased first and then decreased. Copper purity increased with the increase of CuSO ·5H O. When the concentration of CuSO ·5H O, NaCl and H SO was respectively 90, 40 and 118 g/L and current density was 80 mA/cm , copper recovery rate and purity was up to 97.32% and 99.86%, respectively. Thus, electrolysis proposes a feasible and prospective approach for waste printed circuit boards recycle, even for e-waste, though more researches are needed for industrial application.

关键词: Waste printed circuit boards (WPCBs)     Copper     Recovery rate     Purity     Electrolysis    

Copper fractal growth during recycling from waste printed circuit boards by slurry electrolysis

《环境科学与工程前沿(英文)》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1405-7

摘要:

• Copper fractal growth was observed during WPCBs recycling by slurry electrolysis.

关键词: Dendritic copper     Fractal growth     WPCBs     Slurry electrolysis    

Thermal cracking of waste printed wiring boards for mechanical recycling by using residual steam preprocessing

Yao CHEN, Jinhui LI, Huabo DUAN, Zhishi WANG

《环境科学与工程前沿(英文)》 2011年 第5卷 第2期   页码 167-174 doi: 10.1007/s11783-011-0308-4

摘要: Mechanical waste-processing methods, which combine crushing and separation processes for the recovery of valuable materials, have been widely applied in waste printed wiring board (PWB) treatment. However, both the high impact toughness and the tensile and flexural strengths of whole PWB with a laminated structure result in great energy consumption and severe abrasion of the cutters during multi-level crushing. In addition, the high temperatures occurring in continual crushing probably cause the decomposition of the polymer matrix. A thermal-crack method using residual steam as the heating medium has been developed to pre-treat waste PWBs. This treatment reduces the mechanical strength in order to improve the recovery rate of valuable materials in subsequent mechanical recycling. The changes of the PWBs’ macro-mechanical properties were studied to evaluate thermal expansion impacts associated with changes in temperature, and the dynamic dislocation micro-structures were observed to identify the fracture mechanism. The results showed that thermal cracking with steam at the temperature of 500 K can effectively attenuate the mechanical properties of waste PWBs, by reducing the impact, tensile and flexural strengths respectively, by 59.2%, 49.3% and 51.4%, compared to untreated PWB. Thermal expansion can also facilitate the separation of copper from glass fiber by reducing peel resistance by 95.4% at 500 K. It was revealed that the flexural fracture was a transverse cracking caused by concentrated stress when the heating temperature was less than 500 K, and shifted to a vertical cracking after exceeding 500 K.

关键词: waste printed wiring board (PWB)     residue steam     thermal-crack     mechanical properties    

A critical review on the recycling of copper and precious metals from waste printed circuit boards using

Zebing Wu, Wenyi Yuan, Jinhui Li, Xiaoyan Wang, Lili Liu, Jingwei Wang

《环境科学与工程前沿(英文)》 2017年 第11卷 第5期 doi: 10.1007/s11783-017-0995-6

摘要: Currently, increasing amounts of end-of-life (EoL) electronic products are being generated due to their reduced life spans and the unavailability of suitable recycling technologies. In particular, waste printed circuit boards (PCBs) have become of global concern with regard to environmental issues because of their high metal and toxic material contents, which are pollutants. There are many environmental threats owed to the disposal of electronic waste; off-gasses, such as dioxins, furans, polybrominated organic pollutants, and polycyclic aromatic hydrocarbons, can be generated during thermal treatments, which can cause serious health problems if effective off-gas cleaning systems are not developed and improved. Moreover, heavy metals will dissolve, and release into the ground water from the landfill sites. Such waste PCBs contain precious metals which are of monetary value. Therefore, it is beneficial to recover the metal content and protect the environment from pollution. Hydrometallurgy is a successful technique used worldwide for the recovery of precious metals (especially gold and silver) from ores, concentrates, and waste materials. It is generally preferred over other methods because it can offer high recovery rates at a relatively low cost. This article reviews the recent trends and developments with regard to the recycling of precious metals from waste PCBs through hydrometallurgical techniques, such as leaching and recovery.

关键词: Waste PCBs     Precious metals     Hydrometallurgy     Recycling     Leaching     Recovery    

基于AOI的印刷电路图像对准算法研究

郭峰林,管庶安,孔岩

《中国工程科学》 2012年 第14卷 第11期   页码 103-106

摘要:

基于AOI的PCB检测系统中,样本PCB图像与待测PCB图像之间存在错位偏差,需要对准后才能进行下一步的检测工作。首先,依据PCB线路特征,定义了样本图像边缘点的概念,制订了边缘点抽样规则。针对待测PCB图像,提出了基于样本边缘点对准强度评价函数,建立了对准评价模型及对准快速算法。最后,通过PCB对准实验以及大量的实际测试应用,证明对准强度评价模型能准确地描述待测PCB图像与样本图像间的对准程度,对准模型为后期的缺陷搜索提供了可靠的偏移参数。

关键词: PCB缺陷检测     图像对准     边缘点抽样     对准强度    

基于新型拓扑Halbach阵列的PCB定子无铁心轴向磁通电机设计 Regular Papers

Xiao-yuan WANG, Xiang LI, Chun-peng LI, Si-jia XU, Le-tao LING

《信息与电子工程前沿(英文)》 2019年 第20卷 第3期   页码 414-424 doi: 10.1631/FITEE.1700345

摘要: 针对印刷电路板(PCB)定子轴向磁通永磁电机特点,提出一种新型拓扑Halbach永磁体阵列,设计并分析应用该永磁体阵列的PCB定子轴向磁通永磁电机。与传统无铁心轴向磁通永磁电机相比,在相同尺寸、同等永磁体用量下,该新型拓扑Halbach永磁体阵列PCB定子轴向磁通永磁电机具有更高气隙磁密及每极磁通,可获得更高空载反电势,同时有效降低漏磁,使气隙磁密更接近正弦波,提升了电机整体性能。有限元分析结果和样机对比实验验证了该新型拓扑Halbach永磁体阵列PCB定子电机的合理性和有效性,为PCB定子轴向磁通永磁电机设计提供了参考依据和工程应用价值。

关键词: 轴向磁通电机;印制电路板;Halbach永磁体阵列;有限元法    

Real-world fuel consumption of light-duty passenger vehicles using on-board diagnostic (OBD) systems

Xuan Zheng, Sheng Lu, Liuhanzi Yang, Min Yan, Guangyi Xu, Xiaomeng Wu, Lixin Fu, Ye Wu

《环境科学与工程前沿(英文)》 2020年 第14卷 第2期 doi: 10.1007/s11783-019-1212-6

摘要: • Fuel consumption (FC) from LDPVs is measured using on-board diagnostic method (OBD). • The FC of the OBD is 7.1% lower than that of the carbon balance results. • The discrepancy between the approved FC and real-world FC is 13%±18%. • There is a strong relationship (R2=0.984) between the average speed and relative FC. An increasing discrepancy between real-world and type-approval fuel consumption for light-duty passenger vehicles (LDPVs) has been reported by several studies. Normally, real-world fuel consumption is measured primarily by a portable emission measurement system. The on-board diagnostic (OBD) approach, which is flexible and offers high-resolution data collection, is a promising fuel consumption monitoring method. Three LDPVs were tested with a laboratory dynamometer based on a type-approval cycle, the New European Driving Cycle (NEDC). Fuel consumption was measured by the OBD and constant-volume sampling system (CVS, a regulatory method) to verify the accuracy of the OBD values. The results of the OBD method and the regulatory carbon balance method exhibited a strong linear correlation (e.g., R2 = 0.906-0.977). Compared with the carbon balance results, the fuel consumption results using the OBD were 7.1%±4.3% lower on average. Furthermore, the real-world fuel consumption of six LDPVs was tested in Beijing using the OBD. The results showed that the normalized NEDC real-world fuel consumption of the tested vehicles was 13%±17% higher than the type-approval-based fuel consumption. Because the OBD values are lower than the actual fuel consumption, using a carbon balance method may result in a larger discrepancy between real-word and type-approval fuel consumption. By means of the operating mode binning and micro trip methods, a strong relationship (R2 = 0.984) was established between the average speed and relative fuel consumption. For congested roads (average vehicle speed less than 25 km/h), the fuel consumption of LDPVs is highly sensitive to changes in average speed.

关键词: Fuel consumption     Light-duty passenger vehicles     On-board diagnostic systems    

Direct writing of electronics based on alloy and metal (DREAM) ink: A newly emerging area and its impact on energy, environment and health sciences

Qin ZHANG, Yi ZHENG, Jing LIU

《能源前沿(英文)》 2012年 第6卷 第4期   页码 311-340 doi: 10.1007/s11708-012-0214-x

摘要: Electronics, such as printed circuit board (PCB), transistor, radio frequency identification (RFID), organic light emitting diode (OLED), solar cells, electronic display, lab on a chip (LOC), sensor, actuator, and transducer etc. are playing increasingly important roles in people’s daily life. Conventional fabrication strategy towards integrated circuit (IC), requesting at least six working steps, generally consumes too much energy, material and water, and is not environmentally friendly. During the etching process, a large amount of raw materials have to be abandoned. Besides, lithography and microfabrication are typically carried out in “Cleanroom” which restricts the location of IC fabrication and leads to high production costs. As an alternative, the newly emerging ink-jet printing electronics are gradually shaping modern electronic industry and its related areas, owing to the invention of a series of conductive inks composed of polymer matrix, conductive fillers, solvents and additives. Nevertheless, the currently available methods also encounter some technical troubles due to the low electroconductivity, complex sythesis and sintering process of the inks. As an alternative, a fundamentally different strategy was recently proposed by the authors’ lab towards truly direct writing of electronics through introduction of a new class of conductive inks made of low melting point liquid metal or its alloy. The method has been named as direct writing of electronics based on alloy and metal (DREAM) ink. A series of functional circuits, sensors, electronic elements and devices can thus be easily written on various either soft or rigid substrates in a moment. With more and more technical progresses and fundamental discoveries being kept made along this category, it was found that a new area enabled by the DREAM ink electronics is emerging, which would have tremendous impacts on future energy and environmental sciences. In order to promote the research and development along this direction, the present paper is dedicated to draft a comprehensive picture on the DREAM ink technology by summarizing its most basic features and principles. Some important low melting point metal ink candidates, especially the room temperature liquid metals such as gallium and its alloy, were collected, listed and analyzed. The merits and demerits between conventional printed electronics and the new direct writing methods were comparatively evaluated. Important scientific issues and technical strategies to modify the DREAM ink were suggested and potential application areas were proposed. Further, digestions on the impacts of the new technology among energy, health, and environmental sciences were presented. Meanwhile, some practical challenges, such as security, environment-friendly feature, steady usability, package, etc. were summarized. It is expected that the DREAM ink technology will initiate a series of unconventional applications in modern society, and even enter into peoples’ daily life in the near future.

关键词: direct writing of electronics based on alloy and metal (DREAM) ink     direct writing of electronics     printed electronics     liquid metal ink     integrated circuit     consumer electronics     nano liquid metal    

螺旋结构冷却塔的塔板设计方法

黄锐

《中国工程科学》 2008年 第10卷 第11期   页码 43-46

摘要:

针对冷却塔中螺旋结构类型的气液交换塔,提出其内部螺旋塔板形状的设计方法,包括塔壁上外螺旋线和塔中心轴管上内螺旋线的位置确定,以及两线之间螺旋曲面板在平面上的拓扑尺寸。通过塔的几何参数确定螺旋曲面板设计的关键参数,可实现扭曲状塔板与塔壁及内轴的准确配合。

关键词: 冷却塔     塔板设计     螺旋曲面     拓扑    

Laser sintering of Cu nanoparticles on PET polymer substrate for printed electronics at different wavelengths

Juan Carlos HERNANDEZ-CASTANEDA, Boon Keng LOK, Hongyu ZHENG

《机械工程前沿(英文)》 2020年 第15卷 第2期   页码 303-318 doi: 10.1007/s11465-019-0562-x

摘要: This study explores the feasibility of different laser systems to sinter screen-printed lines from nonconductive copper nanoparticles (Cu NPs) on polyethylene terephthalate polymer film. These materials are commonly used in manufacturing functional printed electronics for large-area applications. Here, optical and thermal characterization of the materials is conducted to identify suitable laser sources and process conditions. Direct diode (808 nm), Nd:YAG (1064 nm and second harmonic of 532 nm), and ytterbium fiber (1070 nm) lasers are explored. Optimal parameters for sintering the Cu NPs are identified for each laser system, which targets low resistivity and high processing speed. Finally, the quality of the sintered tracks is quantified, and the laser sintering mechanisms observed under different wavelengths are analyzed. Practical considerations are discussed to improve the laser sintering process of Cu NPs.

关键词: laser sintering     copper nanoparticles     printed electronics    

单边直线感应电机等效电路参数研究

徐伟,孙广生

《中国工程科学》 2008年 第10卷 第8期   页码 76-80

摘要:

单边直线感应电机(SLIM)相对于旋转感应电机(RIM)存在气隙大、边缘效应等,若采用RIM开路和短路试验方法,会给参数测量带来较大误差。文章提出的一种适合SLIM参数测定的新型方案,只需测量电机输入端的总功率、相电压、相电流和频率4个量,即可计算出初级电阻、初级漏感、次级电阻、次级漏感、气隙电感和铁损电阻。电机的特性分析表明,该方法真实有效,具有一定的参考价值。

关键词: 单边直线感应电机     开路试验     短路试验     参数测量     等效电路    

Equivalent circuit and characteristic simulation of a brushless electrically excited synchronous wind

Hao WANG, Fengge ZHANG, Tao GUAN, Siyang YU

《机械工程前沿(英文)》 2017年 第12卷 第3期   页码 420-426 doi: 10.1007/s11465-017-0439-9

摘要:

A brushless electrically excited synchronous generator (BEESG) with a hybrid rotor is a novel electrically excited synchronous generator. The BEESG proposed in this paper is composed of a conventional stator with two different sets of windings with different pole numbers, and a hybrid rotor with powerful coupling capacity. The pole number of the rotor is different from those of the stator windings. Thus, an analysis method different from that applied to conventional generators should be applied to the BEESG. In view of this problem, the equivalent circuit and electromagnetic torque expression of the BEESG are derived on the basis of electromagnetic relation of the proposed generator. The generator is simulated and tested experimentally using the established equivalent circuit model. The experimental and simulation data are then analyzed and compared. Results show the validity of the equivalent circuit model.

关键词: wind power     brushless electrically excited synchronous generator     hybrid rotor     equivalent circuit    

Printability and hardening performance of three-dimensionally-printed geopolymer based on lunar regolith

《结构与土木工程前沿(英文)》 doi: 10.1007/s11709-023-0003-0

摘要: Using an in situ lunar regolith as a construction material in combination with 3D printing not only reduces the weight of materials carried from the Earth but also improves the automation of lunar infrastructure construction. This study aims to improve the printability of a geopolymer based on a BH-1 lunar regolith simulant, including the extrudability, open time, and buildability, by controlling the temperature and adding admixtures. Rheological parameters were used to represent printability with different water-to-binder ratios, printing temperatures, and contents of additives. The mechanical properties of the hardening geopolymer with different filling paths and loading directions were tested. The results show that heating the printed filaments with a water-to-binder ratio of 0.32 at 80 °C can adjust the printability without adding any additive, which can reduce the construction cost of lunar infrastructure. The printability of the BH-1 geopolymer can also be improved by adding 0.3% Attagel-50 and 0.5% polypropylene fiber by mass at a temperature of 20 °C to cope with the changeable environmental conditions on the Moon. After curing under a simulated lunar environment, the 72-h flexural and compressive strengths of the geopolymer specimens reach 4.1 and 48.1 MPa, respectively, which are promising considering that the acceleration of gravity on the Moon is 1/6 of that on the Earth.

关键词: geopolymer     lunar regolith simulant     3D printing     rheology     printability    

标题 作者 时间 类型 操作

Self-catalytic pyrolysis thermodynamics of waste printed circuit boards with co-existing metals

期刊论文

Non-toxic, high selectivity process for the extraction of precious metals from waste printed circuit

期刊论文

Copper recovery from waste printed circuit boards concentrated metal scraps by electrolysis

Xiaonan Liu, Qiuxia Tan, Yungui Li, Zhonghui Xu, Mengjun Chen

期刊论文

Copper fractal growth during recycling from waste printed circuit boards by slurry electrolysis

期刊论文

Thermal cracking of waste printed wiring boards for mechanical recycling by using residual steam preprocessing

Yao CHEN, Jinhui LI, Huabo DUAN, Zhishi WANG

期刊论文

A critical review on the recycling of copper and precious metals from waste printed circuit boards using

Zebing Wu, Wenyi Yuan, Jinhui Li, Xiaoyan Wang, Lili Liu, Jingwei Wang

期刊论文

基于AOI的印刷电路图像对准算法研究

郭峰林,管庶安,孔岩

期刊论文

基于新型拓扑Halbach阵列的PCB定子无铁心轴向磁通电机设计

Xiao-yuan WANG, Xiang LI, Chun-peng LI, Si-jia XU, Le-tao LING

期刊论文

Real-world fuel consumption of light-duty passenger vehicles using on-board diagnostic (OBD) systems

Xuan Zheng, Sheng Lu, Liuhanzi Yang, Min Yan, Guangyi Xu, Xiaomeng Wu, Lixin Fu, Ye Wu

期刊论文

Direct writing of electronics based on alloy and metal (DREAM) ink: A newly emerging area and its impact on energy, environment and health sciences

Qin ZHANG, Yi ZHENG, Jing LIU

期刊论文

螺旋结构冷却塔的塔板设计方法

黄锐

期刊论文

Laser sintering of Cu nanoparticles on PET polymer substrate for printed electronics at different wavelengths

Juan Carlos HERNANDEZ-CASTANEDA, Boon Keng LOK, Hongyu ZHENG

期刊论文

单边直线感应电机等效电路参数研究

徐伟,孙广生

期刊论文

Equivalent circuit and characteristic simulation of a brushless electrically excited synchronous wind

Hao WANG, Fengge ZHANG, Tao GUAN, Siyang YU

期刊论文

Printability and hardening performance of three-dimensionally-printed geopolymer based on lunar regolith

期刊论文